热点突破5 用数形结合思想理解“铝三角”
[解题策略] Al3+、Al(OH)3、AlO之间的转化关系(“铝三角”)
写出上述转化的离子方程式:
(1)①Al3++3NH3·H2O===Al(OH)3↓+3NH;②Al3++3AlO+6H2O===4Al(OH)3↓;
③Al3++3OH-===Al(OH)3↓;
(2)Al(OH)3+3H+===Al3++3H2O;
(3)Al3++4OH-===AlO+2H2O;
(4)AlO+4H+===Al3++2H2O;
(5)①AlO+CO2+2H2O===Al(OH)3↓+HCO;②AlO+H++H2O===Al(OH)3↓
(6)Al(OH)3+OH-===AlO+2H2O